Open Access

Table 1

Summary of the effect of operating parameters on H2/CO2 to methanol.

Type of catalyst Type of reactor T (°C)/P (MPa) CO2 conversion (%) MeOH selectivity (%) MeOH yield (%) STY of MeOH (gMeOH/gcat h) Ref
CuO–Fe2O3–3%CeO2/HZSM-5 Fixed-bed 260/3 20.9 5.2 N/A N/A [8]
CuO–Fe2O3–4%CeO2/HZSM-5 Fixed-bed 260/3 17.1 4.6 N/A N/A [8]
CuO/ZnO/Al2O3-C-1 Fixed-bed 240/3 14.6 63.6 9.3 0.12 [27]
CuO/ZnO/Al2O3-C-1.25 Fixed-bed 240/3 16.2 63.8 10.3 0.13 [27]
CuO/ZnO/Al2O3-O-1 Fixed-bed 240/3 12.1 62.6 7.8 0.10 [27]
CuO/ZnO/Al2O3-U-1 Fixed-bed 240/3 3.2 53.9 1.7 0.022 [27]
Cu/ZnO/ZrO2-0 Fixed-bed 230/5 16.7 54.7 N/A 0.14 [28]
Cu/ZnO/ZrO2-5 Fixed-bed 230/5 15.4 66.8 N/A 0.16 [28]
Cu/ZnO/ZrO2-0 Fixed-bed 270/5 22.5 51.8 N/A 0.18 [28]
Cu/ZnO/ZrO2-5 Fixed-bed 270/5 23.0 56.8 N/A 0.21 [28]
5%CuZn/rGO Fixed-bed 250/1.5 14 2.8 N/A 0.22 [54]
10%CuZn/rGO Fixed-bed 250/1.5 26 5.1 N/A 0.424 [54]
20%CuZn/rGO Fixed-bed 250/1.5 19 8.5 N/A 0.244 [54]
CuZnGa Fixed-bed 270/3 15.8 N/A 29.3 0.135 [55]
Cu/0.5%MgO/TiO2 Fixed-bed 220/3 5.0 33.9 1.70 N/A [58]
Cu/1%MgO/TiO2 Fixed-bed 220/3 5.2 37.9 1.97 N/A [58]
Cu/5%MgO/TiO2 Fixed-bed 220/3 2.6 55.5 1.44 N/A [58]
Cu/TiO2 Fixed-bed 220/3 4.3 29.8 1.28 N/A [58]
Cu-Zn/SiO2 Fixed-bed 250/2 2.0 65.7 N/A 0.065 [67]
10Cu60Zn30 Fixed-bed 250/1.5 21 83 N/A 0.274 [68]
Fe–Cu/MCM-41 Fixed-bed 200/1 2 80 N/A N/A [69]
Cu–ZnO/TiO2–ZrO2 Fixed-bed 240/3 17.4 43.8 7.6 0.053 [70]

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