Supplementary Material
Figure S1. Scheme of the NOC (from real feedstocks, oil-derived middle distillates) adsorption system used. Packed bed (MIL-101(Cr) extrudates) operating at room temperature, atmospheric pressure (78 kPa) and LHSV = 0.6–1.5 h−1. Figure S2. N2 physisorption isotherm (−198 °C) of as-prepared MOF MIL-101(Cr) synthesized with propylene oxide as proton scavenger. Filled squares: Adsorption branch; Open squares: Desorption branch. Figure S3. X-ray diffraction pattern of as-prepared MOF MIL-101(Cr) synthesized with propylene oxide as proton scavenger. Figure S4. Thermogravimetrical (a) and differential thermogravimetrical (b) profiles of prepared MIL-101(Cr) extrudates. Figure S5. UV-vis spectrum of extruded adsorbent MIL-101(Cr) prepared with propylene oxide. Figure S6. Infrared spectrum of extruded adsorbent MIL-101(Cr) prepared with propylene oxide. Figure S7. Raman spectra of various analyzed zones of extruded adsorbent MIL-101(Cr) prepared with propylene oxide. Figure S8. SEM micrographs of extruded MOF MIL-101(Cr) material at various magnifications. (a) 200×; (b) 2000×; (c) 100 000×; (d) 120 000×. (Access here)
© E. Meneses-Ruiz et al., published by IFP Energies nouvelles, 2021