Table 2
Evolution of the 4-nonyne metathesis rate versus the activation time of [Mo2Cl2(NO)2] n
Activation time (min) | 5 | 10 | 20 | 30 | 40 | 50 | 60 |
---|---|---|---|---|---|---|---|
TOF (h−1) | 57 | 78 | 200 | 360 | 385 | 465 | 516 |
Conditions: Same as in Table 1, toluene as solvent. T = 60°C.