Table 4
Parameters of the Boolean models of nano-particles (prism and sphere). The sphere radius is 2.5 nm The last column De is the effective diffusion coefficients of the Boolean models estimated with the numerical FFT method.
| Particle shape | Pore volume fraction |
Platelet shape (nm) |
Effective diffusion |
|||
|---|---|---|---|---|---|---|
| ε | D1 | D2 | D3 | D4 | De | |
| Sphere | 0.7 | 0.566 | ||||
| Cubic prism | 0.7 | 3.9 | 0.1 | 3.9 | 4.0 | 0.540 |
| Platelet-like prism | 0.7 | 7.0 | 0.1 | 2.9 | 3.0 | 0.533 |
| Rod-like prism | 0.7 | 1.9 | 0.1 | 1.9 | 16.0 | 0.518 |