Table 3
Results of the elemental analysis and Rock-Eval pyrolysis. TOC = Total Organic Carbon; TIC = Total Inorganic Carbon; TS = Total Sulfur; T max = temperature at the peak of S2; HI = Hydrogen Index (S2/TOC × 100); OI = Oxygen Index (S3/TOC × 100); [–]: not determined.
Sample | TOC [wt.%] | TIC [wt.%] | TS [wt.%] | S1 [mg HC/g rock] | S2 [mg HC/g rock] | S3 [mg C02/g rock] | Tmax [°C] | Hl [mg HC/g TOC] | Ol [mg C02/g TOC] |
---|---|---|---|---|---|---|---|---|---|
15/892 | 0.48 | 5.07 | 0.17 | 0.02 | 0.12 | 1.31 | 260 | 25 | 273 |
15/893 | 0.76 | 8.02 | 0.19 | 0.02 | 0.17 | 1.32 | 260 | 22 | 174 |
15/894 | 0.96 | 3.55 | 0.2 | 0.02 | 0.20 | 1.29 | 391 | 21 | 134 |
17/1679 | 5.43 | 9.20 | 0.03 | 0.77 | 25.23 | 4.94 | 415 | 465 | 91 |
15/863 | 7.12 | 9.32 | 1.04 | 0.63 | 36.35 | 1.46 | 416 | 511 | 21 |
17/1680 | 5.84 | 8.99 | 1.05 | 0.72 | 27.67 | 5.36 | 415 | 474 | 92 |
17/1681 | 7.39 | 8.65 | 0.99 | 0.33 | 24.69 | 3.69 | 412 | 334 | 50 |
15/864 | 7.23 | 9.42 | 1.09 | 0.39 | 35.74 | 1.47 | 412 | 494 | 20 |
17/1682 | 7.19 | 8.51 | 0.15 | 0.32 | 27.02 | 2.11 | 415 | 376 | 29 |
15/865 | 9.33 | 8.68 | 1.16 | 0.68 | 49.70 | 3.00 | 413 | 533 | 32 |
17/1683 | 4.34 | 5.05 | 0.66 | 0.30 | 11.68 | 1.60 | 423 | 269 | 37 |
15/866 | 3.99 | 6.20 | 0.67 | 0.31 | 17.72 | 1.42 | 421 | 444 | 36 |
15/867 | 3.55 | 6.37 | 0.54 | 0.18 | 14.29 | 1.48 | 416 | 403 | 42 |
17/1685 | 4.88 | 5.79 | 0.58 | 0.16 | 10.24 | 2.77 | 415 | 210 | 57 |
17/1686 | 4.07 | 4.24 | 0.62 | 0.20 | 11.87 | 1.66 | 422 | 292 | 41 |
15/868 | 3.73 | 5.25 | 0.69 | 0.16 | 16.87 | 1.45 | 421 | 452 | 39 |
15/869 | 5.08 | 9.97 | 0.84 | 0.18 | 27.79 | 1.43 | 421 | 547 | 28 |
17/1687 | 6.20 | 8.22 | 1.01 | 0.19 | 22.52 | 2.31 | 416 | 363 | 37 |
15/870 | 6.16 | 9.16 | 0.98 | 0.24 | 31.60 | 1.40 | 416 | 513 | 23 |
17/1688 | 4.92 | 8.69 | 0.95 | 0.28 | 22.56 | 4.08 | 415 | 459 | 83 |
15/871 | 5.85 | 9.44 | 0.98 | 0.22 | 30.68 | 1.45 | 419 | 524 | 25 |
17/1689 | 4.31 | 9.09 | 0.68 | 0.17 | 15.69 | 1.74 | 420 | 364 | 40 |
15/872 | 4.80 | 10.00 | 0.66 | 0.17 | 24.73 | 1.43 | 419 | 515 | 30 |
15/873 | 4.99 | 9.89 | 0.78 | 0.17 | 25.43 | 1.43 | 416 | 510 | 29 |
17/1690 | 3.80 | 9.52 | 0.63 | 0.17 | 15.94 | 3.57 | 419 | 419 | 94 |
15/874 | 4.57 | 10.45 | 0.59 | 0.27 | 23.77 | 1.51 | 415 | 520 | 33 |
17/1691 | 3.13 | 7.65 | 0.65 | 0.22 | 7.67 | 1.47 | 425 | 245 | 47 |
17/1692 | 0.70 | 10.32 | 0.23 | 0.06 | 0.64 | 0.79 | 423 | 91 | 112 |
15/875 | 1.19 | 10.61 | 0.31 | 0.07 | 3.33 | 1.25 | 422 | 280 | 105 |
17/1693 | 1.63 | 9.34 | 0.27 | 0.08 | 3.49 | 1.11 | 428 | 214 | 68 |
15/876 | 2.35 | 7.79 | 0.36 | 0.15 | 8.70 | 1.50 | 424 | 370 | 64 |
17/1694 | 1.58 | 4.65 | 0.31 | 0.11 | 4.12 | 1.45 | 421 | 261 | 92 |
15/877 | 0.67 | 9.71 | 0.26 | 0.04 | 0.49 | 1.33 | 420 | 73 | 199 |
17/1696 | 0.96 | 6.81 | 0.30 | 0.04 | 0.45 | 1.84 | 423 | 46 | 192 |
17/1698 | 0.46 | 10.00 | 0.20 | 0.03 | 0.45 | 0.66 | 424 | 97 | 143 |
17/1699 | 0.58 | 10.28 | 0.20 | 0.03 | 0.43 | 0.80 | 423 | 74 | 139 |
17/1700 | 0.56 | 10.04 | 0.17 | 0.03 | 0.54 | 0.77 | 425 | 96 | 137 |
17/1701 | 0.22 | 1.52 | 0.11 | 0.00 | 0.10 | 0.74 | 426 | 45 | 332 |
17/1702 | 0.94 | 9.78 | 0.41 | 0.03 | 1.22 | 0.87 | 425 | 129 | 93 |
17/1703 | 0.81 | 9.80 | 0.32 | 0.04 | 0.75 | 0.82 | 426 | 92 | 101 |
17/1704 | 0.66 | 10.25 | 0.20 | 0.04 | 0.58 | 1.12 | 425 | 88 | 170 |
17/1705 | 0.33 | 10.30 | 0.22 | 0.00 | 1.05 | 1.38 | 425 | 318 | 418 |
17/1706 | 0.70 | 10.14 | 0.23 | 0.04 | 0.88 | 0.85 | 423 | 125 | 121 |
17/1707 | 0.09 | 10.61 | 0.16 | 0.00 | 0.21 | 0.75 | 424 | 233 | 833 |
17/1708 | 0.12 | 2.05 | 0.16 | 0.01 | 0.24 | 0.94 | 423 | 200 | 783 |
17/1709 | 0.75 | 10.58 | 0.24 | 0.05 | 1.07 | 1.08 | 424 | 143 | 144 |
17/1711 | 0.55 | 10.63 | 0.29 | 0.05 | 0.89 | 0.71 | 426 | 161 | 130 |
17/1712 | 0.40 | 10.14 | 0.28 | 0.04 | 0.44 | 0.84 | 421 | 110 | 211 |
17/1715 | 1.32 | 9.21 | 0.61 | 0.03 | 1.89 | 1.78 | 428 | 143 | 135 |
15/878 | 0.62 | 11.94 | 0.24 | 0.03 | 0.95 | 1.32 | 428 | 153 | 213 |
17/1717 | 0.64 | 10.95 | 0.27 | 0.07 | 0.71 | 0.90 | 429 | 429 | 111 |
15/879 | 0.70 | 11.55 | 0.27 | 0.04 | 1.18 | 1.35 | 429 | 429 | 169 |
15/880 | 0.96 | 11.06 | 0.30 | 0.05 | 1.71 | 1.36 | 428 | 428 | 178 |
15/881 | 0.71 | 11.78 | 0.25 | 0.04 | 1.09 | 1.37 | 427 | 427 | 154 |
17/1718 | 0.84 | 10.54 | 0.26 | 0.11 | 0.94 | 1.12 | 429 | 429 | 112 |
15/882 | 0.60 | 11.88 | 0.29 | 0.03 | 1.04 | 1.37 | 428 | 428 | 173 |
15/883 | 0.82 | 11.48 | 0.28 | 0.04 | 1.93 | 1.36 | 434 | 434 | 235 |
15/884 | 0.65 | 11.91 | 0.19 | 0.03 | 0.99 | 1.40 | 427 | 427 | 152 |
17/1720 | 0.09 | 11.25 | 0.12 | 0.00 | 0.08 | 0.97 | 421 | 421 | 89 |
17/1721 | 0.31 | 11.53 | 0.15 | 0.06 | 0.58 | 0.69 | 430 | 430 | 187 |
15/885 | 0.95 | 11.11 | 0.33 | 0.04 | 2.17 | 1.31 | 426 | 426 | 228 |
15/886 | 1.28 | 11.12 | 0.31 | 0.04 | 2.76 | 1.31 | 427 | 427 | 216 |
17/1722 | 0.58 | 10.52 | 0.33 | 0.01 | 1.72 | 1.24 | 426 | 426 | 297 |
15/887 | 0.81 | 10.26 | 0.32 | 0.03 | 1.16 | 1.35 | 428 | 428 | 143 |
17/1724 | 1.13 | 0.01 | 0.36 | 0.04 | 1.03 | 1.25 | 426 | 426 | 91 |
15/888 | 0.97 | 10.43 | 0.36 | 0.04 | 1.56 | 1.29 | 428 | 428 | 161 |
17/1726 | 1.45 | 9.67 | 0.47 | 0.03 | 2.29 | 1.79 | 428 | 429 | 111 |
15/889 | 1.75 | 10.39 | 0.43 | 0.06 | 4.25 | 1.30 | 430 | 429 | 169 |
17/1727 | 1.85 | 9.17 | 0.51 | 0.04 | 1.03 | 1.25 | 425 | 428 | 178 |
15/890 | 2.16 | 10.21 | 0.41 | 0.09 | 6.82 | 1.63 | 430 | 427 | 154 |
15/891 | 1.98 | 11.03 | 0.36 | 0.11 | 6.81 | 1.36 | 423 | 429 | 112 |
17/1729 | 0.73 | 10.28 | 0.22 | 0.04 | 0.65 | 1.03 | 426 | 428 | 173 |
17/1732 | 0.84 | 9.73 | 0.28 | 0.04 | 0.60 | 0.96 | 426 | 434 | 235 |
17/1733 | 0.14 | 10.71 | 0.15 | 0.02 | 0.36 | 0.79 | 425 | 427 | 152 |
17/1735 | 0.96 | 9.50 | 0.34 | 0.04 | 0.75 | 1.45 | 425 | 421 | 89 |
17/1736 | 0.30 | 9.69 | 0.41 | 0.00 | 0.42 | 1.02 | 424 | 430 | 187 |
17/1737 | 0.22 | 10.50 | 0.81 | 0.01 | 0.19 | 0.78 | 417 | 426 | 228 |
17/1738 | 0.82 | 9.10 | 0.81 | 0.04 | 0.55 | 1.03 | 422 | 427 | 216 |
17/1740 | 0.94 | 8.90 | 0.55 | 0.09 | 0.68 | 1.22 | 421 | 426 | 297 |
17/1742 | 0.41 | 11.35 | 0.18 | 0.04 | 0.49 | 0.81 | 428 | 428 | 143 |
17/1743 | 0.47 | 9.45 | 0.36 | 0.03 | 1.11 | 1.74 | 426 | 426 | 91 |
15/895 | 3.72 | 9.40 | 0.27 | 0.07 | 9.41 | 1.54 | 423 | 428 | 161 |
17/1744 | 0.03 | 0.06 | — | — | — | — | — | — | — |
17/1745 | 0.70 | 9.19 | 0.18 | — | — | — | — | — | — |
17/1746 | 0.71 | 6.16 | 0.17 | — | — | — | — | — | — |
17/1747 | 0.91 | 7.41 | 0.17 | — | — | — | — | — | — |
17/1748 | 2.29 | 0.06 | 0.42 | — | — | — | — | — | — |
15/896 | 0.52 | 11.91 | 0.19 | 0.03 | 0.44 | 1.30 | 426 | 426 | 85 |
17/1749 | 0.48 | 10.81 | 0.19 | 0.03 | 0.44 | 1.30 | 426 | 421 | 59 |
17/1751 | 0.12 | 11.00 | 0.11 | — | — | — | — | — | — |
17/1752 | 0.23 | 11.37 | — | — | — | — | — | — | — |
17/1753 | 0.27 | 11.33 | — | — | — | — | — | — | — |
17/1754 | 0.20 | 11.50 | — | — | — | — | — | — | — |
17/1755 | 0.28 | 11.44 | — | — | — | — | — | — | — |
17/1756 | 0.15 | 11.63 | — | — | — | — | — | — | — |
17/1757 | 0.23 | 11.76 | — | — | — | — | — | — | — |
17/1758 | 0.18 | 11.08 | 0.16 | — | — | — | — | — | — |
17/1759 | 0.22 | 11.79 | — | — | — | — | — | — | — |
17/1760 | 0.27 | 11.77 | — | — | — | — | — | — | — |
17/1761 | 0.26 | 11.86 | — | — | — | — | — | — | — |
17/1762 | 0.04 | 12.49 | — | — | — | — | — | — | — |
15/897 | 0.63 | 12.15 | 0.22 | 0.04 | 2.19 | 1.34 | 427 | 427 | 348 |
15/898 | 0.95 | 12.24 | 0.19 | 0.06 | 2.57 | 1.28 | 425 | 425 | 271 |
15/899 | 2.04 | 11.80 | 0.36 | 0.18 | 9.91 | 1.58 | 419 | 419 | 486 |
17/1763 | 0.38 | 11.76 | 0.15 | 0.04 | 0.55 | 1.03 | 422 | 424 | 183 |
15/900 | 0.79 | 12.10 | 0.25 | 0.05 | 2.61 | 1.31 | 425 | 425 | 330 |
17/1764 | 0.88 | 10.91 | 0.21 | 0.08 | 2.71 | 0.72 | 421 | 421 | 308 |
15/901 | 1.00 | 12.55 | 0.22 | 0.06 | 3.36 | 1.30 | 424 | 424 | 336 |
17/1765 | 0.55 | 10.87 | 0.20 | 0.02 | 2.39 | 0.82 | 424 | 424 | 435 |
15/902 | 3.57 | 11.20 | 0.51 | 0.23 | 20.25 | 1.57 | 413 | 413 | 567 |
17/1766 | 2.48 | 9.96 | 0.61 | 0.16 | 13.08 | 2.16 | 414 | 414 | 527 |
15/903 | 3.62 | 10.82 | 0.54 | 0.19 | 20.98 | 1.57 | 414 | 414 | 580 |
17/1767 | 2.19 | 10.37 | 0.62 | 0.16 | 10.83 | 2.09 | 415 | 415 | 495 |
15/904 | 4.20 | 11.06 | 0.56 | 0.33 | 23.62 | 1.59 | 412 | 412 | 562 |
15/905 | 2.56 | 11.49 | 0.36 | 0.14 | 13.48 | 1.56 | 418 | 418 | 527 |
17/1768 | 0.32 | 11.91 | 0.13 | 0.05 | 0.67 | 0.54 | 422 | 422 | 208 |
15/906 | 2.04 | 11.58 | 0.38 | 0.11 | 10.61 | 1.58 | 416 | 416 | 520 |
17/1769 | 0.38 | 11.83 | 0.11 | 0.06 | 1.03 | 0.49 | 423 | 423 | 271 |
17/1770 | 0.36 | 11.25 | 0.12 | 0.02 | 1.42 | 0.55 | 423 | 423 | 394 |
17/1771 | 0.91 | 11.70 | 0.18 | 0.08 | 3.13 | 0.73 | 423 | 423 | 344 |
17/1772 | 0.37 | 11.85 | 0.10 | 0.05 | 1.04 | 0.47 | 424 | 424 | 283 |