Dossier: Special Issue in Tribute to Yves Chauvin
Open Access

Table 3

Effect of alkyne/Mo ratio on reaction rate on the MoO2(acac)2/AlEt3/PhOH catalyst at 110°C

4-nonyne/Mo 10 100 200 500 1000 1500 2000
TOF (h−1) 650 7000 12700 32000 62500 100250 144000

Conditions: solvent: toluene; [Mo] = 10−3M; [AlEt3]/[Mo] = 6; [PhOH] = 10−1M; T = 110°C.

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