Figure 1.
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Thermal ellipsoid (50% probability) of the structure of 1. Hydrogen atoms and mesityl groups on thiolate have been omitted for clarity. Selected bond distance (Å) and angles (deg): W1-N1 = 1.7486(17), W1-O1 = 1.9212(14), W1-O2 = 2.4404(15), W1-S1 = 2.3930(5), W1-C1 = 1.915(2); O1-W1-O2 = 68.90(6), O1-W1-S1 = 138.88(5), O1-W1-N1 = 103.18(7), O1-W1-C1 = 111.83(8), O2-W1-N1 = 171.80(7), O2-W1-C1 = 83.94(7), O2-W1-S1 = 81.11(4), S1-W1-N1 = 104.73(6), S1-W1-C1 = 91.43(7), C1-W1-N1 = 101.47(9).